Year 2011, Volume 31 , Issue 3, Pages 775 - 791 2011-09-01

The Determination of Dopamine and Uric Acid with the Presence of Other Using Square Wave Voltammetry
Dopamin ve Ürik Asitin Birinin Varlığında Diğerinin Kare Dalga Voltametrisi ile Tayini

Erdoğan HASDEMİR [1] , Tuğba TABANLIGİL [2]


Initially the electrochemical behavior of dopamine (DA) and uric acid (UA) in different supporting electrolytes was investigated. It was found that the most suitable supporting electrolytes were pH 2.5 H2SO4 and pH 7.2 phosphate buffer. The analysis of DA and UA in acidic medium was carried out by the use of their oxidation peaks observed at +0.480 V and +0.620 V, respectively. The analysis of the phosphate buffer medium were carried out by the use of the oxidation peaks of DA and UA appeared at +0.140 V and +0.270 V, respectively. The studies carried out with different [DA] / [UA] ratios gave acceptable results for both media. The synthetic sample was analyzed. The error was -0.41 % for DA and 0.27 % for UA in acidic media and -0.61 % for DA and -0.14 % for UA in basic media. The limits of detection (LOD) were found as 2.16 × 10-8 M and 4.14 × 10-8 M in acidic media, 2.28 × 10-8 M and 2.13 × 10-8 M in basic media for DA and UA, respectively.
Bu çalışmada çeşitli destek elektrolit ortamlarında DA ve ÜA' nın yükseltgenme davranışları incelenmiş, pH 2,5 H2SO4 ve pH 7,2 fosfat tamponunun uygun olduğuna karar verilmiştir. pH 2,5 H2SO4 ortamında DA ve ÜA' nın sırasıyla +0,480 V, +0,620 V' da ki, fosfat tamponunda da sırasıyla +0,140 V, +0,270 V' da ki yükseltgenme pikleri kullanılmıştır. Her iki ortamda farklı [DA] / [ÜA] oranları çalışılmıştır. Sentetik numune için, pH 2,5 H2SO4 ortamında DA ve ÜA için % hata sırasıyla -0,41 ve 0,27, pH 7,2 fosfat tamponu ortamında aynı numune için % hata sırasıyla -0,61 ve -0,14 olarak bulunmuştur. pH 2,5 H2SO4 ortamında DA ve ÜA için gözlenebilme sınırı (LOD) sırasıyla 2,16 × 10-8 M ve 4,14 × 10-8 M, tayin sınırı (LOQ) ise 6,48 × 10-8 M ve 1,24 × 10-7 M olarak bulunmuştur. pH 7,2 fosfat tamponu ortamında DA ve ÜA için gözlenebilme sınırı (LOD) sırasıyla 2,28 × 10-8 M ve 2,13 × 10-8 M, tayin sınırı (LOQ) 6,84 × 10-8 M ve 6,39 × 10-8 M olarak bulunmuştur. Bu yönteme çeşitli anyon ve katyonların
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Primary Language tr
Journal Section Articles
Authors

Author: Erdoğan HASDEMİR

Author: Tuğba TABANLIGİL

Dates

Publication Date : September 1, 2011

Bibtex @ { gefad90567, journal = {Gazi Üniversitesi Gazi Eğitim Fakültesi Dergisi}, issn = {1301-9058}, address = {}, publisher = {Gazi University}, year = {2011}, volume = {31}, pages = {775 - 791}, doi = {}, title = {Dopamin ve Ürik Asitin Birinin Varlığında Diğerinin Kare Dalga Voltametrisi ile Tayini}, key = {cite}, author = {HASDEMİR, Erdoğan and TABANLIGİL, Tuğba} }
APA HASDEMİR, E , TABANLIGİL, T . (2011). Dopamin ve Ürik Asitin Birinin Varlığında Diğerinin Kare Dalga Voltametrisi ile Tayini. Gazi Üniversitesi Gazi Eğitim Fakültesi Dergisi , 31 (3) , 775-791 . Retrieved from http://www.gefad.gazi.edu.tr/en/issue/6737/90567
MLA HASDEMİR, E , TABANLIGİL, T . "Dopamin ve Ürik Asitin Birinin Varlığında Diğerinin Kare Dalga Voltametrisi ile Tayini". Gazi Üniversitesi Gazi Eğitim Fakültesi Dergisi 31 (2011 ): 775-791 <http://www.gefad.gazi.edu.tr/en/issue/6737/90567>
Chicago HASDEMİR, E , TABANLIGİL, T . "Dopamin ve Ürik Asitin Birinin Varlığında Diğerinin Kare Dalga Voltametrisi ile Tayini". Gazi Üniversitesi Gazi Eğitim Fakültesi Dergisi 31 (2011 ): 775-791
RIS TY - JOUR T1 - Dopamin ve Ürik Asitin Birinin Varlığında Diğerinin Kare Dalga Voltametrisi ile Tayini AU - Erdoğan HASDEMİR , Tuğba TABANLIGİL Y1 - 2011 PY - 2011 N1 - DO - T2 - Gazi Üniversitesi Gazi Eğitim Fakültesi Dergisi JF - Journal JO - JOR SP - 775 EP - 791 VL - 31 IS - 3 SN - 1301-9058- M3 - UR - Y2 - 2019 ER -
EndNote %0 Gazi Üniversitesi Gazi Eğitim Fakültesi Dergisi Dopamin ve Ürik Asitin Birinin Varlığında Diğerinin Kare Dalga Voltametrisi ile Tayini %A Erdoğan HASDEMİR , Tuğba TABANLIGİL %T Dopamin ve Ürik Asitin Birinin Varlığında Diğerinin Kare Dalga Voltametrisi ile Tayini %D 2011 %J Gazi Üniversitesi Gazi Eğitim Fakültesi Dergisi %P 1301-9058- %V 31 %N 3 %R %U
ISNAD HASDEMİR, Erdoğan , TABANLIGİL, Tuğba . "Dopamin ve Ürik Asitin Birinin Varlığında Diğerinin Kare Dalga Voltametrisi ile Tayini". Gazi Üniversitesi Gazi Eğitim Fakültesi Dergisi 31 / 3 (September 2011): 775-791 .
AMA HASDEMİR E , TABANLIGİL T . Dopamin ve Ürik Asitin Birinin Varlığında Diğerinin Kare Dalga Voltametrisi ile Tayini. Gazi Üniversitesi Gazi Eğitim Fakültesi Dergisi. 2011; 31(3): 775-791.
Vancouver HASDEMİR E , TABANLIGİL T . Dopamin ve Ürik Asitin Birinin Varlığında Diğerinin Kare Dalga Voltametrisi ile Tayini. Gazi Üniversitesi Gazi Eğitim Fakültesi Dergisi. 2011; 31(3): 791-775.